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Total result(s) found: 6
  • Controlled Acrylate Insertion Regioselectivity in Diazaphospholidine-Sulfonato Palladium(II) Complexes
    P. Wucher, P. Roesle, L. Falivene, L. Cavallo, L. Caporaso, I. Goettker-Schnetmann, S. Mecking
    Organometallics 31, 8505, (2012)
Keywords:
Active catalyst, Bulky substituents, Cis isomers, DFT study, Ethylene polymerization, Insertion products, Linear polyethylene, Lutidine, Methyl acrylates, Norbornenes, P-tolyl, Palladium complexes, Transition state
  • Synthesis of 3-Fluoro-3-aryl Oxindoles: Direct Enantioselective a Arylation of Amides
    L. Wu, L. Falivene, E. Drinkel, S. Grant, A. Linden, L. Cavallo, R. Dorta
    Angew. Chem. Int. Ed. 51, 2870, (2012)
Keywords:
Asymmetric catalysis, N-heterocyclic carbenes, Oxindoles, Palladium, Synthetic methods
  • Mechanistic Features of Isomerizing Alkoxycarbonylation of Methyl Oleate
    P. Roesle, C.J. Duerr, H.M. Moeller, L. Cavallo, L. Caporaso, S. Mecking
    J. Am. Chem. Soc. 134, 17696, (2012)
Keywords:
1-forms, 1-octene, Alkoxycarbonylation, DFT study, Diesters, Ester carbonyl group, Hydride species, Isomer distributions, Mechanistic studies, Methanolysis, Methyl oleate, Reactive precursors, Terminal olefins, Triflates
  • Investigating Alkoxysilane Coverage and Dynamics on the (104) and (110) Surfaces of MgCl2-Supported Ziegler-Natta Catalysts
    R. Credendino, J.T.M. Pater, D. Liguori, G. Morini, L. Cavallo
    J. Phys. Chem. C 116, 22980, (2012)
Keywords:
Alkoxysilanes, Coordination properties, Donor molecules, Low energies, Migration pathway, Steric repulsions, Surface coverages, Ziegler-Natta catalysts
  • π-Face Donation from the Aromatic N-Substituent of N-Heterocyclic Carbene Ligands to Metal and Its Role in Catalysis
    R. Credendino, L. Falivene, L. Cavallo
    J. Am. Chem. Soc. 134, 8127, (2012)
Keywords:
Cross-couplings, D orbitals, Electron-deficient, Electron-donating, Energy decomposition, Model reactions, N-heterocyclic carbene ligands, NHC ligands, Olefin metathesis, Oxidation state, Oxidized state, Para position, Reaction pathways, Redox potentials
  • Stereoselectivity in Metallocene-Catalyzed Coordination Polymerization of Renewable Methylene Butyrolactones: From Stereo-random to Stereo-perfect Polymers
    X. Chen, L. Caporaso, L. Cavallo, E.Y.X. Chen
    J. Am. Chem. Soc. 134, 7278, (2012)
Keywords:
Butyrolactones, Catalyst structures, Computational studies, Coordination polymerization, Polymerization reaction, Stereo-regular polymer, Stereocontrol, Zirconocene catalyst