Mechanochemically assembled organometallic complexes: a mechanistic study
byLama Hamdouna, Gianmarco Pisanò, Andrew G. M. Rankin, Julien Trébosc, Ida Ritacco, Olivier Devos, Laurent Delevoye, Pascal Roussel, Lucia Caporaso, Luigi Cavallo, Steven P. Nolan, Olivier Lafon, Catherine S. J. Cazin
Year:2026DOI:10.1039/D6SC01038E
Extra Information
Chemical Science
Abstract
A combination of mechanical synthesis, solid-state
analytical techniques (ssNMR, powder XRD, ATR-FTIR) and DFT calculations
sheds light on the mechanisms operating in two organometallic
solid-state syntheses and highlight the importance of workup protocols
in mechanochemical syntheses. The data clearly indicate that product
formation can occur during or post grinding.
