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2012
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Publications
Controlled Acrylate Insertion Regioselectivity in Diazaphospholidine-Sulfonato Palladium(II) Complexes
Year:
2012
ISSN:
02767333
Authors:
P. Wucher, P. Roesle, L. Falivene, L. Cavallo, L. Caporaso, I. Goettker-Schnetmann, S. Mecking
Active catalyst
Bulky substituents
Cis isomers
DFT study
Ethylene polymerization
Insertion products
Linear polyethylene
Lutidine
Methyl acrylates
Norbornenes
P-tolyl
Palladium complexes
Transition state
Synthesis of 3-Fluoro-3-aryl Oxindoles: Direct Enantioselective a Arylation of Amides
Year:
2012
ISSN:
14337851
Authors:
L. Wu, L. Falivene, E. Drinkel, S. Grant, A. Linden, L. Cavallo, R. Dorta
Asymmetric catalysis
N-heterocyclic carbenes
Oxindoles, Palladium
Synthetic methods
Mechanistic Features of Isomerizing Alkoxycarbonylation of Methyl Oleate
Year:
2012
ISSN:
00027863
Authors:
P. Roesle, C.J. Duerr, H.M. Moeller, L. Cavallo, L. Caporaso, S. Mecking
1-forms, 1-octene
Alkoxycarbonylation
DFT study
Diesters
Ester carbonyl group
Hydride species
Isomer distributions
Mechanistic studies
Methanolysis
Methyl oleate
Reactive precursors
Terminal olefins
Triflates
Investigating Alkoxysilane Coverage and Dynamics on the (104) and (110) Surfaces of MgCl2-Supported Ziegler-Natta Catalysts
Year:
2012
ISSN:
19327447
Authors:
R. Credendino, J.T.M. Pater, D. Liguori, G. Morini, L. Cavallo
Alkoxysilanes
Coordination properties
Donor molecules
Low energies
Migration pathway
Steric repulsions
Surface coverages
Ziegler-Natta catalysts
π-Face Donation from the Aromatic N-Substituent of N-Heterocyclic Carbene Ligands to Metal and Its Role in Catalysis
Year:
2012
ISSN:
00027863
Authors:
R. Credendino, L. Falivene, L. Cavallo
Cross-couplings
D orbitals
Electron-deficient
Electron-donating
Energy decomposition
Model reactions
N-heterocyclic carbene ligands
NHC ligands
Olefin metathesis
Oxidation state
Oxidized state
Para position
Reaction pathways
Redox potentials
Stereoselectivity in Metallocene-Catalyzed Coordination Polymerization of Renewable Methylene Butyrolactones: From Stereo-random to Stereo-perfect Polymers
Year:
2012
ISSN:
00027863
Authors:
X. Chen, L. Caporaso, L. Cavallo, E.Y.X. Chen
Butyrolactones
Catalyst structures
Computational studies
Coordination polymerization
Polymerization reaction
Stereo-regular polymer
Stereocontrol
Zirconocene catalyst